First (3,6)-connected framework constructed from sandwich-type polyoxometalate building blocks containing novel octa-copper cluster

نویسندگان

  • Jun-Wei Zhao
  • Jie Zhang
  • Guo-Yu Yang
چکیده

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Construction of polyoxometalates from dynamic lacunary polyoxotungstate building blocks and lanthanide linkers.

A series of polynuclear metal-oxo clusters have been constructed from the dynamic polyoxometalate (POM) building block {B-α-Sb(III)W9O33} and lanthanide (Ln) linkers via a stepwise synthetic strategy with the molecular formulas of [Ln2(H2O)4{WO2(pic)}2(SbW8O30)2](10-) (Na4Li6[La-1]·28H2O, Na3Li7[Pr-2]·30H2O) and [{Ln(H2O)}{Ln(pic)}(Sb3O4)(SbW8O31)(SbW10O35)]2(24-) (K2Na6Li16[Tb-3]·63H2O, Na9Li1...

متن کامل

Reversible redox reactions in an extended polyoxometalate framework solid.

Extended modular frameworks that incorporate inorganic building blocks represent a new field of research where “active sites” can be engineered to respond to guest inclusion. This process can initiate highly specific chemical reactions that switch the overall nature of the framework, and it may even be developed to facilitate directed chemical reactions similar to those found in enzymatic syste...

متن کامل

Organic functionalization of polyoxometalate in aqueous solution: self-assembly of a new building block of {VMo6O25} with triethanolamine.

A novel organic-inorganic hybrid of triethanolamine linked covalently with a new building block of {VMo6O25} was synthesized in aqueous solution, and the hybrid was further assembled with copper-triethanolamine complexes to form a ring-like structure. This work represents an advance in the organic functionalization of polyoxometalate performed in aqueous solution instead of an organic solvent.

متن کامل

Structure-related frustrated magnetism of nanosized polyoxometalates: aesthetics and properties in harmony.

The structural versatility characterizing polyoxometalate chemistry, in combination with the option to deliberately use well-defined building blocks, serves as the foundation for the generation of a large family of magnetic clusters, frequently comprising highly symmetric spin arrays. If the spin centers are coupled by antiferromagnetic exchange, some of these systems exhibit spin frustration, ...

متن کامل

Self-assembly of nanometre-scale metallacalix[4]arene building blocks and Keggin units to a novel (3,4)-connected 3D self-penetrating framework.

A novel (3,4)-connected 3D self-penetrating metal-organic framework with a nanometre-scale cavity constructed from metallacalix[4]arene building blocks and Keggin-type polyanions has been obtained by using a 1,3-bis(1-methyl-5-mercapto-1,2,3,4-tetrazole)propane ligand.

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2007